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Display information for equation id:math.2573.25 on revision:2573

* Page found: Spezifische Wärme zweiatomiger idealer Gase (eq math.2573.25)

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\begin{align}

& {{Z}_{r}}\approx \int_{0}^{\infty }{{}}dl(2l+1)\exp \left( -\frac{{{\Theta }_{r}}}{T}l(l+1) \right) \\

& \frac{{{\Theta }_{r}}}{T}l(l+1):=x \\

& \Rightarrow {{Z}_{r}}\approx \frac{T}{{{\Theta }_{r}}}\int_{0}^{\infty }{{}}dx{{e}^{-x}}=\frac{T}{{{\Theta }_{r}}} \\

& \Rightarrow {{U}_{r}}=-N\frac{\partial }{\partial \beta }\ln {{Z}_{r}}=Nk{{T}^{2}}\frac{\partial }{\partial T}\ln {{Z}_{r}}\approx NkT \\

& \Rightarrow {{c}_{vr}}={{N}_{A}}k=R \\

\end{align}

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MathML (3.859 KB / 619 B) :

Zr0dl(2l+1)exp(ΘrTl(l+1))ΘrTl(l+1):=xZrTΘr0dxex=TΘrUr=NβlnZr=NkT2TlnZrNkTcvr=NAk=R
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